V. M. Mamaev, I. P. Gloriozov, V. V. Simonyan, E. V. Zernova, E. M. Myshakin, Yu. V. Babin, “Tunnelling effects in the oxidative addition of a dihydrogen molecule to the palladium ethylenediphosphine complexes [H2P(CH2)2PH2]Pd and [H2P(CH2)2PH2]Pd2”, Mendeleev Commun., 2000, Volume 10, Issue 1,Pages 12

This article is cited in 2 papers

Tunnelling effects in the oxidative addition of a dihydrogen molecule to the palladium ethylenediphosphine complexes [H₂P(CH₂)₂PH₂]Pd and [H₂P(CH₂)₂PH₂]Pd₂

V. M. Mamaev^a, I. P. Gloriozov^a, V. V. Simonyan^a, E. V. Zernova^a, E. M. Myshakin^a, Yu. V. Babin^b

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Far Eastern State Academy of Economics and Management, Vladivostok, Russian Federation

Abstract: In terms of the reaction-path Hamiltonian formalism, the ligand environment has been found to have almost no effect on the activation barrier in the oxidative addition of H₂ to the title complexes (the under-barrier tunnelling in the reaction was predominant at T < 230 K).

Language: English

DOI: 10.1070/MC2000v010n01ABEH001205