R. G. Kostyanovsky, A. P. Avdeenko, S. A. Konovalova, G. K. Kadorkina, A. V. Prosyanik, “Spontaneous resolution of new conglomerates in the series of 4-arenesulfonyliminocyclohex-2-en-1-ones”, Mendeleev Commun., 2000, Volume 10, Issue 1,Pages <nobr>16

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Spontaneous resolution of new conglomerates in the series of 4-arenesulfonyliminocyclohex-2-en-1-ones

R. G. Kostyanovsky^a, A. P. Avdeenko^b, S. A. Konovalova^b, G. K. Kadorkina^a, A. V. Prosyanik^c

^a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^b Donbass State Machinery Academy, Kramatorsk, Ukraine
^c Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine

Abstract: Racemic mixtures 1a–f, 2a–e crystallise as conglomerates at room temperature and lead to spontaneous resolution; tosylimines 1e and 2c give homochiral crystals (space group P1), whereas similar benzenesulfonyloximes 3a,b give heterochiral packings (space groups P2₁/n and P2₁/c, respectively).

Language: English

DOI: 10.1070/MC2000v010n01ABEH001208