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JOURNALS // Mendeleev Communications // Archive
Mendeleev Commun., 2000 Volume 10, Issue 1, Pages 23–25 (Mi mendc4363)
A new procedure for estimating the enthalpies of formation for RCH2·free radicals

Yu. D. Orlova, V. V. Takhistovb

a Department of Physics and Technology, Tver State University, Tver, Russian Federation
b St. Petersburg Scientific Centre of Ecological Safety, Russian Academy of Sciences, St. Petersburg, Russian Federation

Abstract: From the observed regularity that for certain substituents the ΔΔHf0 values for Me• → RCH2• free radicals and CH2=CH2 → → RCH=CH2 molecules are nearly identical, new or corrected values for the enthalpies of formation were estimated for about 30 gaseous free radicals and molecules.

Language: English

DOI: 10.1070/MC2000v010n01ABEH001122



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