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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2000 Volume 10, Issue 1, Pages 36–37 (Mi mendc4371)

This article is cited in 5 papers

An unusual 3,4-dihydroisoquinoline ring enlargement with the annulation of pyrazole

Yu. V. Shklyaeva, V. A. Glushkova, V. V. Davidovb, V. I. Sokolc, V. S. Sergienkoc

a Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences, Perm, Russian Federation
b Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation
c N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The treatment of substituted ethyl 1-(3’,4’-dihydro-3’,3’-dimethylisoquinolyl)-1-oximinoacetates with hydrazine hydrate leads to a 3,4-dihydroisoquinoline ring enlargement with the annulation of a pyrazole ring to form substituted 5,5-dimethyl-2,3,5,6-tetrahydro- 3-oxopyrazolo[3,4-b]benzo-3-azepines.

Language: English

DOI: 10.1070/MC2000v010n01ABEH001167



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