R. G. Kostyanovsky, V. R. Kostyanovsky, G. K. Kadorkina, V. Yu. Torbeev, “Resolution of racemates with achiral reagents”, Mendeleev Commun., 2000, Volume 10, Issue 3,Pages <nobr>83

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Resolution of racemates with achiral reagents

R. G. Kostyanovsky^a, V. R. Kostyanovsky^a, G. K. Kadorkina^a, V. Yu. Torbeev^b

^a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^b Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Abstract: The conditions required for resolving racemates into enantiomers by crystallization involve a deficiency of either the conglomerator or the achiral solubiliser to promote the solubility of the compound to be resolved; in both cases the resolution can also be achieved by internal entrainment, adding a single crystal of the resolvable conglomerate.

Language: English

DOI: 10.1070/MC2000v010n03ABEH001330