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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2000 Volume 10, Issue 3, Pages 86–88 (Mi mendc4397)

This article is cited in 2 papers

Outer-sphere anion–anion charge transfer in a solid hexacyanoferrate

S. I. Gorel'skiia, T. G. Kimb, T. P. Klimovac, V. Yu. Kotovb, B. V. Lokshinc, Yu. D. Perfil'evd, T. I. Sherbakd, G. A. Tsirlinad

a Department of Chemistry, York University, Toronto, Canada
b Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
d Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: A solid solution based on Cs2Mg[Fe(CN)6] containing both [Fe(CN)6]4– and [Fe(CN)6]3– ions exhibits a green colour associated with electronic absorption spectra bands due to the outer-sphere charge transfer between complex anions.

Language: English

DOI: 10.1070/MC2000v010n03ABEH001280



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