Yu. A. Serguchev, L. F. Lourie, M. V. Ponomarenko, “Selective transannular cyclization of 3,7-bismethylenebicyclo[3.3.1]nonane with F-TEDA-BF<sub>4</sub> in protic solvents”, Mendeleev Commun., 2000, Volume 10, Issue 3,Pages <nobr>121

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Selective transannular cyclization of 3,7-bismethylenebicyclo[3.3.1]nonane with F-TEDA-BF₄ in protic solvents

Yu. A. Serguchev, L. F. Lourie, M. V. Ponomarenko

Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

Abstract: The reaction of 3,7-bismethylenebicyclo[3.3.1]nonane with 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) F-TEDA-BF₄ in protic solvents ROH affords 1-RO-3-fluoromethyladamantanes (R = H, Alk, Ac).

Language: English

DOI: 10.1070/MC2000v010n03ABEH001278