S. V. Chapyshev, R. Walton, P. M. Lahti, “New quintet carbenonitrene system formed in the photolysis of 2,6-bis(4,5-dimethoxycarbonyl-1<i>H</i>-1,2,3-triazolo)-4-azido-3,5-dichloropyridine”, Mendeleev Commun., 2000, Volume 10, Issue 4,Pages <nobr>138

This article is cited in 8 papers

New quintet carbenonitrene system formed in the photolysis of 2,6-bis(4,5-dimethoxycarbonyl-1H-1,2,3-triazolo)-4-azido-3,5-dichloropyridine

S. V. Chapyshev^a, R. Walton^b, P. M. Lahti^b

^a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b Department of Chemistry, University of Massachusetts, Amherst, USA

Abstract: New triplet pyridyl-4-nitrene, triplet pyridyl-2-imidoylcarbene and quintet 4-nitrenopyridyl-2-imidoylcarbene have been detected by EPR spectroscopy after photolysis of 2,6-bis(4,5-dimethoxycarbonyl-1H-1,2,3-triazolo)-4-azido-3,5-dichloropyridine at 77 K.

Language: English

DOI: 10.1070/MC2000v010n04ABEH001309