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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2000 Volume 10, Issue 4, Pages 157–159 (Mi mendc4434)

This article is cited in 8 papers

Synthesis and thermal decomposition of organosilicon hexamine cobalt-containing xerogels

V. V. Semenova, L. G. Klapshinaa, W. E. Douglasb, G. A. Domracheva

a G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
b Laboratoire de structure et dynamique des systemes moleculaires et solides, Departement chimie, Universite Montpellier II, France

Abstract: The treatment of 3-aminopropyltriethoxysilane (APTES) with Co2(CO)8 resulted in hexa(3-aminopropyltriethoxysilane)cobalt(II) bis(tetracarbonylcobaltate) 1, the co-hydrolysis of which with APTES, tetraethoxysilane, MeSi(OMe)3 and HO(Me2SiO)nOH afforded cobalt-containing xerogels or transparent films.

Language: English

DOI: 10.1070/MC2000v010n04ABEH001221



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