RUS  ENG
Full version
JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2023 Volume 33, Issue 4, Pages 512–514 (Mi mendc444)

This article is cited in 1 paper

Communications

Catalytic cyclopropanation of hexa-1,3,5-triene with diazomethane as a simple synthesis of high-energy tercyclopropane

E. V. Shulishov, O. A. Pantyukh, L. G. Menchikov, Yu. V. Tomilov

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A simple method for a preparing of tercyclopropane or 1,2-dicyclopropylethene by the catalytic cyclo-propanation of hexa-1,3,5-triene with diazomethane has been developed. Thermochemical characteristics for tercyclopropane show that it may be a candidate to replace syntin as a propellant for spacecraft engines.

Keywords: cyclopropane, tercyclopropane, diazomethane, liquid fuels, strained hydrocarbons, syntin.

Language: English

DOI: 10.1016/j.mencom.2023.06.023



Bibliographic databases:


© Steklov Math. Inst. of RAS, 2025