V. A. Alfonsov, G. A. Bakaleynik, A. T. Gubaidullin, V. E. Kataev, G. I. Kovyljaeva, A. I. Konovalov, I. A. Litvinov, I. Yu. Strobykina, O. V. Andreeva, M. G. Korochkina, “The first example of the supramolecular regulation of amidophosphite reactivity”, Mendeleev Commun., 2000, Volume 10, Issue 5,Pages <nobr>177–178</nobr>

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Mendeleev Commun., 2000 Volume 10, Issue 5, Pages 177–178 (Mi mendc4444)

The first example of the supramolecular regulation of amidophosphite reactivity

V. A. Alfonsov^a, G. A. Bakaleynik^a, A. T. Gubaidullin^a, V. E. Kataev^a, G. I. Kovyljaeva^a, A. I. Konovalov^b, I. A. Litvinov^a, I. Yu. Strobykina^a, O. V. Andreeva^a, M. G. Korochkina^a

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

Abstract: The cyclophosphorylation of calix[4]resorcinolarenes by aromatic diamides of phosphorous acid follows an anomalous pathway with opening of the P–O bond and preservation of one of the P–N bonds due to the interaction between the aromatic nuclei of the phosphorus-containing fragment and the calixarene matrix of the intermediate phosphorylated calixarene.

Language: English

DOI: 10.1070/MC2000v010n05ABEH001362

Fulltext: PDF file (278 kB)

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