L. Ya. Zakharova, F. G. Valeeva, L. A. Kudryavtseva, A. I. Konovalov, “The kinetics of solvolysis of <i>p</i>-nitrophenyl bis(chloromethyl)phosphinate in a micellar solution of sodium dodecyl sulfate in ethylene glycol: catalysis by metal ions”, Mendeleev Commun., 2000, Volume 10, Issue 6,Pages <nobr>241

This article is cited in 3 papers

The kinetics of solvolysis of p-nitrophenyl bis(chloromethyl)phosphinate in a micellar solution of sodium dodecyl sulfate in ethylene glycol: catalysis by metal ions

L. Ya. Zakharova^a, F. G. Valeeva^a, L. A. Kudryavtseva^a, A. I. Konovalov^b

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

Abstract: A 30-fold acceleration of the title reaction due to an increase in the activation entropy and activation enthalpy in the micellar pseudophase compared to ethylene glycol was found; Mg²⁺, Zn²⁺ and La³⁺ ions accelerate the solvolysis by factors of 5, 8 and 20, respectively.

Language: English

DOI: 10.1070/MC2000v010n06ABEH001337