V. V. Gorbatchuk, A. G. Tsifarkin, I. S. Antipin, B. N. Solomonov, A. I. Konovalov, “Influence of the guest molecular size on the thermodynamic parameters of host–guest complexes between solid <i>tert</i>-butylcalix[4]arene and vapours of organic compounds”, Mendeleev Commun., 1999, Volume 9, Issue 1,Pages <nobr>11

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Influence of the guest molecular size on the thermodynamic parameters of host–guest complexes between solid tert-butylcalix[4]arene and vapours of organic compounds

V. V. Gorbatchuk^a, A. G. Tsifarkin^a, I. S. Antipin^a, B. N. Solomonov^a, A. I. Konovalov^b

^a Department of Chemistry, V.I. Ul'yanov-Lenin Kazan State University, Kazan, Russian Federation
^b Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

Abstract: The shape of guest molecules has a significantly greater influence on the free energy of supramolecular effect in the formation of solid complexes of tert-butylcalix[4]arene than on their stoichiometry.

Language: English

DOI: 10.1070/MC1999v009n01ABEH000989