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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1999 Volume 9, Issue 2, Pages 54–55 (Mi mendc4523)

This article is cited in 4 papers

EPR study of the reaction of C60 with chlorine dioxide: experimental evidence for the formation of the C60 radical cation

V. I. Sokolova, V. V. Bashilova, Q. K. Timerghazinb, E. V. Avzyanovab, A. F. Khalizovb, N. M. Shishlovb, V. V. Shereshovetsb

a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
b Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Abstract: The interaction of chlorine dioxide with fullerene C60 affords a brown precipitate, and its EPR spectrum exhibits an asymmetric singlet signal (g = 2.0029, ΔHpp = 0.2 mT) tentatively assigned to the fullerene radical cation.

Language: English

DOI: 10.1070/MC1999v009n02ABEH001046



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