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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1999 Volume 9, Issue 2, Pages 83–85 (Mi mendc4537)

This article is cited in 2 papers

Interaction in olefin–NO+ complexes: structure and dynamics of the NO+–2,3-dimethyl-2-butene complex

G. I. Borodkin, I. R. Elanov, A. M. Genaev, M. M. Shakirov, V. G. Shubin

N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: 1H and 13C NMR studies involving the 13C NMR deuterium perturbation method and ab initio calculations showed the interaction between 2,3-dimethyl-2-butene and the nitrosonium cation to form a dynamic π-complex.

Language: English

DOI: 10.1070/MC1999v009n02ABEH000995



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