E. B. Averina, T. S. Kuznetsova, A. N. Zefirov, A. E. Koposov, Yu. K. Grishin, N. S. Zefirov, “Reaction of 2,2-dibromotricyclo[7.1.01,9.01,3]decane with methyllithium: synthesis of bicyclo[7.1.0]decadiene-1,2 and dibromotriangulane rearrangement”, Mendeleev Commun., 1999, Volume 9, Issue 3,Pages 101

This article is cited in 7 papers

Reaction of 2,2-dibromotricyclo[7.1.0^1,9.0^1,3]decane with methyllithium: synthesis of bicyclo[7.1.0]decadiene-1,2 and dibromotriangulane rearrangement

E. B. Averina^a, T. S. Kuznetsova^a, A. N. Zefirov^a, A. E. Koposov^b, Yu. K. Grishin^a, N. S. Zefirov^a

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Department of Chemistry, University of Minnesota Duluth, Duluth, Minnesota, USA

Abstract: Reaction of 2,2-dibromotricyclo[7.1.0^1,9.0^1,3]decane with methyllithium gives strained cyclic allene 1 containing an ethenylidenecyclopropane unit in a nine-membered ring and dimer 6 resulting from a dibromotriangulane rearrangement.

Language: English

DOI: 10.1070/MC1999v009n03ABEH001078