V. M. Mamaev, I. P. Gloriozov, A. V. Prisyajnuk, Yu. V. Babin, “Kinetic isotope effects in the activation of H–H bonds by palladium clusters”, Mendeleev Commun., 1999, Volume 9, Issue 4,Pages <nobr>136–139</nobr>

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Mendeleev Commun., 1999 Volume 9, Issue 4, Pages 136–139 (Mi mendc4563)

Kinetic isotope effects in the activation of H–H bonds by palladium clusters

V. M. Mamaev^a, I. P. Gloriozov^a, A. V. Prisyajnuk^b, Yu. V. Babin^c

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Far Eastern Federal University, Vladivostok, Russian Federation
^c Far Eastern State Academy of Economics and Management, Vladivostok, Russian Federation

Abstract: The mechanism of oxidative dihydrogen addition to palladium clusters has been analysed in terms of the reaction-path Hamiltonian approximation, and the abnormal H/D kinetic isotope effect has been explained.

Language: English

DOI: 10.1070/MC1999v009n04ABEH001094

Fulltext: PDF file (223 kB)

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