U. Jordis, M. Kesselgruber, S. Nerdinger, K. Mereiter, “New 2,5-diazabicyclo[2.2.1]heptanes and their application in the asymmetric addition of diethylzinc to benzaldehyde”, Mendeleev Commun., 1999, Volume 9, Issue 4,Pages <nobr>147

This article is cited in 7 papers

New 2,5-diazabicyclo[2.2.1]heptanes and their application in the asymmetric addition of diethylzinc to benzaldehyde

U. Jordis^a, M. Kesselgruber^a, S. Nerdinger^a, K. Mereiter^b

^a Institut fuer Organische Chemie der TU Wien, Wien, Austria
^b Institut fuer Mineralogie, Kristallographie und Strukturchemie der TU Wien, Wien, Austria

Abstract: New (1S,4S)-2,5-diazabicyclo[2.2.1]heptane derivatives synthesised by directed ortho metalation result in enantioselectivities of up to 78% e.e. when used as catalysts in the addition of diethylzinc to benzaldehyde.

Language: English

DOI: 10.1070/MC1999v009n04ABEH001088