S. A. Mitchenko, E. V. Khomutov, V. V. Kovalenko, A. F. Popov, I. P. Beletskaya, “Generation of platinum(III) species by mechanical treatment of solid K2PtX6 (X = Cl, Br) salts”, Mendeleev Commun., 1999, Volume 9, Issue 5,Pages 171

This article is cited in 4 papers

Generation of platinum(III) species by mechanical treatment of solid K₂PtX₆ (X = Cl, Br) salts

S. A. Mitchenko^a, E. V. Khomutov^b, V. V. Kovalenko^b, A. F. Popov^b, I. P. Beletskaya^c

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b L.M. Litvinenko Institute of Physical Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, Donetsk, Ukraine
^c Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: A mechanical treatment of the solid salts K₂PtX₆ containing a small admixture of K₂PtX₄ (X = Cl, Br) in the atmosphere of air or argon leads to the formations of paramagnetic platinum d⁷-complexes.

Language: English

DOI: 10.1070/MC1999v009n05ABEH001116