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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1999 Volume 9, Issue 5, Pages 173–175 (Mi mendc4582)

This article is cited in 2 papers

Complexation of ruthenium with glucose oxidase modified by 4-pyridineacetic and 4-imidazoleacetic acids

V. N. Gorala, E. Csoeregib, B. Mattiassonb, A. D. Ryabovc

a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b Department of Biotechnology, Center for Chemistry and Chemical Engineering, Lund University, Lund, Sweden
c G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation

Abstract: Glucose oxidase (GO) conjugated with 4-pyridineacetic and 4-imidazoleacetic acids reacted with cis-[Ru(bpy)2Cl2] to afford the Ru-containing catalytically active species Ru–X–GO (X = pyridine or imidazole) capable of the intramolecular electron transfer from reduced FAD to an electrochemically generated RuIII centre.

Language: English

DOI: 10.1070/MC1999v009n05ABEH001162



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