S. V. Barkanova, E. A. Makarova, O. L. Kaliya, E. A. Luk'yanets, “Manganese tetraazaporphines as effective catalysts for the nuclear oxidation of aromatics by peracetic acid”, Mendeleev Commun., 1999, Volume 9, Issue 5,Pages <nobr>177

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Manganese tetraazaporphines as effective catalysts for the nuclear oxidation of aromatics by peracetic acid

S. V. Barkanova, E. A. Makarova, O. L. Kaliya, E. A. Luk'yanets

Russian Research Centre 'Research Institute of Organic Intermediates and Dyes', Moscow, Russian Federation

Abstract: Manganese tetranitrotetra-tert-butyltetraazaporphine at low concentrations (0.02 mol%) effectively catalyses the oxidation of 2-methylnaphthalene by peracetic acid to give 2-methyl-1,4-naphthoquinone in 65% yield with a catalyst turnover number of 3100.

Language: English

DOI: 10.1070/MC1999v009n05ABEH001165