V. Yu. Kotov, G. A. Tsirlina, “Close contact distance between hexacyanometallate ions in the course of electron transfer”, Mendeleev Commun., 1999, Volume 9, Issue 5,Pages <nobr>181

This article is cited in 6 papers

Close contact distance between hexacyanometallate ions in the course of electron transfer

V. Yu. Kotov^a, G. A. Tsirlina^b

^a Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: On the basis of rate constants of redox reactions and stability constants of anion pairs, the contact distances between hexacyanometallate ions in the course of electron transfer were estimated as 6.7–7.1 Å, these values are comparable with the contact anion–anion distances in solids and subtantially lower than the sum of radii of nonhydrated ions.

Language: English

DOI: 10.1070/MC1999v009n05ABEH001138