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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1999 Volume 9, Issue 5, Pages 198–199 (Mi mendc4595)

This article is cited in 6 papers

The first efficient electrophilic carbonylation of ethane with carbon monoxide

A. V. Orlinkov, I. S. Akhrem, S. V. Vitt

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Ethane reacts with CO without solvent in the presence of polyhalomethane·2AlBr3 superelectrophilic systems to form EtCOOR after alcoholysis together with small amounts of corresponding esters of 1- and 2-bromopropanoic acids.

Language: English

DOI: 10.1070/MC1999v009n05ABEH001163



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