S. K. Dedushenko, Yu. D. Perfil'ev, D. Chebukov, D. A. Pankratov, Yu. M. Kiselev, “A Mössbauer study of pentavalent iron in a vanadium(V) oxide matrix”, Mendeleev Commun., 1999, Volume 9, Issue 5,Pages <nobr>211–212</nobr>

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Mendeleev Commun., 1999 Volume 9, Issue 5, Pages 211–212 (Mi mendc4602)

This article is cited in 6 papers

A Mössbauer study of pentavalent iron in a vanadium(V) oxide matrix

S. K. Dedushenko^a, Yu. D. Perfil'ev^b, D. Chebukov^bc, D. A. Pankratov^b, Yu. M. Kiselev^b

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^c N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The formation of iron in the 5+ oxidation state was observed in iron-doped vanadium(V) oxide; this state is characterised by a singlet with the isomer shift δ = –0.56±0.01 mm s^–1 relative to α-iron in the Mössbauer spectrum at room temperature.

Language: English

DOI: 10.1070/MC1999v009n05ABEH001157

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