V. A. Maksakov, V. P. Kirin, A. V. Virovets, P. A. Petukhov, A. V. Tkachev, “Transformation of diaminocarane on a triosmium cluster. Absolute configuration of a cluster with a bridging imidyl ligand”, Mendeleev Commun., 1999, Volume 9, Issue 6,Pages <nobr>213–214</nobr>

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Mendeleev Commun., 1999 Volume 9, Issue 6, Pages 213–214 (Mi mendc4603)

This article is cited in 3 papers

Transformation of diaminocarane on a triosmium cluster. Absolute configuration of a cluster with a bridging imidyl ligand

V. A. Maksakov^a, V. P. Kirin^a, A. V. Virovets^a, P. A. Petukhov^b, A. V. Tkachev^c

^a A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b Department of Natural Sciences, Novosibirsk State University, Novosibirsk, Russian Federation
^c N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: The C–H activation of an NMe₂ group in diaminocarane coordinated to an Os₃ cluster results in the formation of (R,S)-{Os₃(CO)₁₀(μ-H){μ,η²(N,C)-(4R,6R,8S,10S)-1,7,7,10-tetramethyl-1,3-diazatricyclo[3.5.0.0]dec-1-en-2-yl}} diastereomers.

Language: English

DOI: 10.1070/MC1999v009n06ABEH001128

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