V. A. Dyatlov, V. G. Kharitonova, D. V. Kupriyanova, E. G. Krivoborodov, I. A. Derevnin, A. I. Kovalev, I. A. Khotina, “Oligomers based on cyanoacrylic acid esters”, Mendeleev Commun., 2023, Volume 33, Issue 4,Pages <nobr>565

This article is cited in 1 paper

Communications

Oligomers based on cyanoacrylic acid esters

V. A. Dyatlov^a, V. G. Kharitonova^b, D. V. Kupriyanova^b, E. G. Krivoborodov^a, I. A. Derevnin^a, A. I. Kovalev^b, I. A. Khotina^b

^a D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Ethyl 3-alkoxy-2-cyanopropanoates were prepared by the reaction of ethyl 2-cyanoacrylate with the corresponding linear alkanols C₆–C₁₂ in acidic medium. Their treatment with water as a weak nucleophile resulted in elimination of the alkanol and the formation of oligocyanoacrylate terminated with the alkoxy group. The oligomers were studied by NMR spectroscopy, IR spectroscopy, MALDI-TOF mass-spectrometry and dynamic light scattering.

Keywords: ethyl 2-cyanoacrylate, fatty alcohols, oligomers, MALDI-TOF mass-spectrometry, nanocapsules, dynamic light scattering.

Language: English

DOI: 10.1016/j.mencom.2023.06.040

	*Supplementary materials:*
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