E. I. Klimova, M. MartinezGarcia, T. Klimova, L. R. Ramirez, J. M. Stivalet, “α-Ferrocenylvinylacetylenes”, Mendeleev Commun., 1999, Volume 9, Issue 6,Pages <nobr>234

This article is cited in 2 papers

α-Ferrocenylvinylacetylenes

E. I. Klimova^a, M. MartinezGarcia^b, T. Klimova^a, L. R. Ramirez^a, J. M. Stivalet^a

^a Materials Research Institute, National Autonomous University of Mexico, Mexico, Mexico
^b Institute of Chemistry, National Autonomous University of Mexico, Mexico, Mexico

Abstract: Thermolysis of 3-isopropyl- and 3-cyclobutyl-3-ferrocenylcyclopropenes results in the formation of 3-alkylidene-3-ferrocenylpropynes and (Z,E)-1-alkyl-1-ferrocenylpropenes; 2,2-dibromo-1-methyl-, 2,2-dibromo-1-isopropyl- and 2,2-dibromo-1-cyclobutylferrocenylcyclopropanes are converted into ferrocenylvinylacetylenes on treatment with Bu^tOK in THF.

Language: English

DOI: 10.1070/MC1999v009n06ABEH001181