G. D. Gamalevich, E. P. Serebryakov, A. L. Vlasyuk, “Lipase-mediated stereodivergent synthesis of both enantiomers of 4-(2,6-dimethylheptyl)benzoic acid”, Mendeleev Commun., 1998, Volume 8, Issue 1,Pages <nobr>8

This article is cited in 4 papers

Lipase-mediated stereodivergent synthesis of both enantiomers of 4-(2,6-dimethylheptyl)benzoic acid

G. D. Gamalevich^a, E. P. Serebryakov^a, A. L. Vlasyuk^b

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Abstract: (S)- and (R)-Enantiomers of methyl 4-(3-hydroxy-2-methylpropyl)benzoate, obtained by enzymatic kinetic resolution of the related racemic arene(tricarbonyl)chromium complex in the vinyl acetate–PPL/Et₂O acylating system, have been converted in four steps into the (R)- and (S)-enantiomers of the title acid, respectively.

Language: English

DOI: 10.1070/MC1998v008n01ABEH000890