M. N. Elinson, S. K. Feducovich, S. G. Bushuev, A. A. Zakharenkov, D. V. Pashchenko, G. I. Nikishin, “Electrochemical transformation of malonate and alkylidenemalonates into 3-substituted cyclopropane-1,1,2,2-tetracarboxylates”, Mendeleev Commun., 1998, Volume 8, Issue 1,Pages <nobr>15–17</nobr>

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Mendeleev Commun., 1998 Volume 8, Issue 1, Pages 15–17 (Mi mendc4632)

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Electrochemical transformation of malonate and alkylidenemalonates into 3-substituted cyclopropane-1,1,2,2-tetracarboxylates

M. N. Elinson^a, S. K. Feducovich^a, S. G. Bushuev^a, A. A. Zakharenkov^a, D. V. Pashchenko^b, G. I. Nikishin^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Abstract: Electrolysis of malonate and alkylidenemalonates in an undivided cell in methanol in the presence of sodium bromide or sodium iodide as mediators leads to substituted 1,1,2,2-cyclopropanetetracarboxylates in 80–95% substance and 60–75% current yield.

Language: English

DOI: 10.1070/MC1998v008n01ABEH000893

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