A. A. Nesterov, A. V. Bashilov, V. K. Runov, N. M. Kuz'min, “An investigation of potassium μ-oxobis[pentachlororuthenium(IV)] in hydrochloric acid solution under microwave irradiation”, Mendeleev Commun., 1998, Volume 8, Issue 3,Pages <nobr>95

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An investigation of potassium μ-oxobis[pentachlororuthenium(IV)] in hydrochloric acid solution under microwave irradiation

A. A. Nesterov^a, A. V. Bashilov^a, V. K. Runov^a, N. M. Kuz'min^b

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b V.I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A study of the ruthenium(IV) and (III) species in HCl solution under microwave irradiation shows a decrease in hydrolysis time, depolymerisation and reduction of ruthenium(IV) to ruthenium(III) by an order of magnitude, as compared with conventional heating of solutions in a boiling water bath.

Language: English

DOI: 10.1070/MC1998v008n03ABEH000920