V. P. Kazakov, A. I. Voloshin, N. M. Shavaleev, “Chemiluminescence of Pr3+ in the visible region from the 3P1, 3P0, 1D2 levels upon decomposition of adamantylideneadamantane-1,2-dioxetane catalysed by β-diketonates Pr(fod)3 and Pr(dpm)3. An unusual route for activator chemiexcitation”, Mendeleev Commun., 1998, Volume 8, Issue 3,Pages 110

This article is cited in 6 papers

Chemiluminescence of Pr³⁺ in the visible region from the ³P₁, ³P₀, ¹D₂ levels upon decomposition of adamantylideneadamantane-1,2-dioxetane catalysed by β-diketonates Pr(fod)₃ and Pr(dpm)₃. An unusual route for activator chemiexcitation

V. P. Kazakov, A. I. Voloshin, N. M. Shavaleev

Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Abstract: Chemiluminescence of Pr³⁺ is observed upon decomposition of adamantylideneadamantane-1,2-dioxetane (AAD) catalysed by β-diketonates Pr(L)₃ (L = fod or dpm), the excitation of Pr³⁺ occurring through intracomplex energy transfer from the excited adamantanone formed upon decomposition of AAD in the complex Pr(L)₃·AAD.

Language: English

DOI: 10.1070/MC1998v008n03ABEH000940