P. A. Stuzhin, O. V. Mal'chugina, S. Wolowiec, L. Latos-Grazynski, B. D. Berezin, “Formation of stable σ-aryliron(III) complexes from the reaction of chloroiron(III) octaphenyltetraazaporphyrinate with aryl Grignard reagents”, Mendeleev Commun., 1998, Volume 8, Issue 4,Pages <nobr>143

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Formation of stable σ-aryliron(III) complexes from the reaction of chloroiron(III) octaphenyltetraazaporphyrinate with aryl Grignard reagents

P. A. Stuzhin^a, O. V. Mal'chugina^b, S. Wolowiec^c, L. Latos-Grazynski^c, B. D. Berezin^b

^a Department of Organic Chemistry, Ivanovo State University of Chemical Technology, Ivanovo, Russian Federation
^b Department of Organic Chemistry, State Academy of Chemistry and Technology, Ivanovo, Russian Federation
^c Department of Chemistry, University of Wroclaw, Wroclaw, Poland

Abstract: Chloro(octaphenyltetraazaporphyrinato)iron(III) [(Cl)Fe^IIIOPTAP] reacts with aryl Grignard reagents (ArMgBr; Ar phenyl or p-tolyl) forming stable low-spin σ-aryliron(III) complexes [(Ar)Fe^IIIOPTAP].

Language: English

DOI: 10.1070/MC1998v008n04ABEH000974