D. V. Kazakov, A. I. Voloshin, V. V. Shereshovets, V. N. Yakovlev, V. P. Kazakov, “Formation of singlet oxygen in the system tris(bipyridine)ruthenium(II)–dimethyldioxirane”, Mendeleev Commun., 1998, Volume 8, Issue 5,Pages <nobr>169

This article is cited in 1 paper

Formation of singlet oxygen in the system tris(bipyridine)ruthenium(II)–dimethyldioxirane

D. V. Kazakov, A. I. Voloshin, V. V. Shereshovets, V. N. Yakovlev, V. P. Kazakov

Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Abstract: Decomposition of dimethyldioxirane in the presence of tris(bipyridine)ruthenium(II) complex (Ru^II) is accompanied by chemiluminescence (CL) in the infrared spectrum region (1270 nm) due to the formation of singlet oxygen; reaction between Ru^III and superoxide ion, which is formed in this process via a sequence of electron-transfer reactions, is assumed to be a CL step.

Language: English

DOI: 10.1070/MC1998v008n05ABEH000936