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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1998 Volume 8, Issue 5, Pages 171–173 (Mi mendc4712)

This article is cited in 6 papers

On-line sorption preconcentration and FIA-FAAS determination of palladium and platinum in solution

L. V. Bogachevaa, I. A. Kovaleva, G. I. Tsysina, A. A. Formanovskyb, Yu. A. Zolotova

a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b M.M. Shemyakin–Yu.A. Ovchinnikov Institute of Bioorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A flow injection flame atomic absorption method for palladium and platinum determination in solution, including sorption preconcentration, has been developed. Preconcentration of platinum metals as ionic associates with n-octyldiethylenetriamine was carried out on ‘reversed phase’ styrene–divinylbenzene copolymer SSPS. RSD 0.03–0.08, detection limits 5 and 3 mg l–1 (Pd and Pt) for 1 min of preconcentration and sampling frequency up to 40 h–1 were achieved.

Language: English

DOI: 10.1070/MC1998v008n05ABEH000959



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