S. G. Dyachkova, E. A. Beskrylaya, A. I. Albanov, L. M. Sinegovskaya, A. G. Malkina, T. A. Skotheim, B. A. Trofimov, “Reaction of thioacetic acid with ethenyl- and ethynyl chlorides”, Mendeleev Commun., 1998, Volume 8, Issue 5,Pages <nobr>185

This article is cited in 2 papers

Reaction of thioacetic acid with ethenyl- and ethynyl chlorides

S. G. Dyachkova^a, E. A. Beskrylaya^a, A. I. Albanov^a, L. M. Sinegovskaya^a, A. G. Malkina^a, T. A. Skotheim^b, B. A. Trofimov^a

^a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
^b Moltech Corporation, Tucson, Arizona, USA

Abstract: Thioacetic acid (TAA) has been subjected to dichlorovinylation with trichloroethene (TCE) under free-radical conditions to form 1-acetylthio-2,2-dichloroethene 1 (yield 70%) which reacts with TAA at room temperature under phase-transfer catalysis conditions to afford a mixture of E- and Z-isomers of 1,2-bis(acetylthio)-2-chloroethene 2 (total yield 71%); ethylthio(chloro)ethyne with sodium thioacetate gives acetylthio(ethylthio)ethyne 3.

Language: English

DOI: 10.1070/MC1998v008n05ABEH000992