V. A. Ershova, S. V. Tkachev, A. V. Golovin, L. Ya. Al't, “The first example of the catalytic activity of (μ-H)Os3(μ-OCNR1R2)(CO)10 clusters in the double bond migration reactions of allylic systems functionalised with an amido group”, Mendeleev Commun., 1998, Volume 8, Issue 6,Pages 208

This article is cited in 4 papers

The first example of the catalytic activity of (μ-H)Os₃(μ-OCNR¹R²)(CO)₁₀ clusters in the double bond migration reactions of allylic systems functionalised with an amido group

V. A. Ershova, S. V. Tkachev, A. V. Golovin, L. Ya. Al't

A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: As exemplified by the isomerisation of N-allylacetamide in the presence of hydridocarbonyl complexes (μ-H)Os₃(μ-OCNR¹R²)(CO)₁₀ (R¹ = H, Alk; R² = Alk), it has been demonstrated for the first time that they are effective catalysts for the [1,2]-double bond shift under mild conditions in allylic compounds functionalised with an amido group.

Language: English

DOI: 10.1070/MC1998v008n06ABEH000962