G. A. Dushenko, I. E. Mikhailov, A. Zschunke, N. Hakam, C. Muegge, V. I. Minkin, “1,7-Sigmatropic shifts of the phenylsulfanyl group along the perimeter of the cycloheptatriene ring”, Mendeleev Commun., 1997, Volume 7, Issue 2,Pages <nobr>50

This article is cited in 12 papers

1,7-Sigmatropic shifts of the phenylsulfanyl group along the perimeter of the cycloheptatriene ring

G. A. Dushenko^a, I. E. Mikhailov^a, A. Zschunke^b, N. Hakam^c, C. Muegge^c, V. I. Minkin^a

^a Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
^b Federal Institute for Materials Research and Testing, Berlin, Germany
^c Department of Chemistry, Humboldt University, Berlin, Germany

Abstract: Rapid and reversible migrations of the phenylsulfanyl group around the seven-membered ring of 7-phenylsulfanylcyclohepta- 1,3,5-triene have been proved to proceed through successive 1,7-sigmatropic shifts with an energy barrier (ΔG^≠₂₉₈) in the range of 19.5−20.1 kcal mol^–1.

Language: English

DOI: 10.1070/MC1997v007n02ABEH000669