R. G. Kostyanovsky, I. I. Chervin, G. K. Kadorkina, K. N. Makarov, L. T. Lantzeva, V. V. Rozhkov, A. V. Prosyanik, “Derivatives of 1-fluoroaziridine-2,2-dicarboxylic acid”, Mendeleev Commun., 1997, Volume 7, Issue 2,Pages <nobr>54

This article is cited in 4 papers

Derivatives of 1-fluoroaziridine-2,2-dicarboxylic acid

R. G. Kostyanovsky^a, I. I. Chervin^a, G. K. Kadorkina^a, K. N. Makarov^b, L. T. Lantzeva^b, V. V. Rozhkov^a, A. V. Prosyanik^c

^a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^c Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine

Abstract: Derivatives of 1-fluoroaziridine-2,2-dicarboxylic acid 10−14 have been synthesized for the first time and characterized by spectroscopic methods; nucleophilic reactions of dimethyl 1-fluoroaziridine-2,2-dicarboxylate, such as transesterification and amidation, occur predominantly at the carboxy group trans-oriented with respect to the N-substituent.

Language: English

DOI: 10.1070/MC1997v007n02ABEH000690