R. G. Kostyanovsky, Yu. I. El'natanov, I. I. Chervin, M. Yu. Antipin, A. V. Ivanov, “Unusual reaction of aziridine dimer with acetylene dicarboxylates”, Mendeleev Commun., 1997, Volume 7, Issue 2,Pages <nobr>56–58</nobr>

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Mendeleev Commun., 1997 Volume 7, Issue 2, Pages 56–58 (Mi mendc4780)

This article is cited in 2 papers

Unusual reaction of aziridine dimer with acetylene dicarboxylates

R. G. Kostyanovsky^a, Yu. I. El'natanov^a, I. I. Chervin^a, M. Yu. Antipin^b, A. V. Ivanov^c

^a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^c A.N. Kosygin Moscow State Textile Academy, Moscow, Russian Federation

Abstract: The 1-(2-aminoethyl)aziridine (aziridine dimer) 1 reacts with acetylene dicarboxylates to give 1,4-diaza- 5-oxobicyclo[4.3.0]nonanes (7-azaindolizines) 3 together with the usual enamine adducts 4; the product structures are confirmed spectroscopically and, in the 3 also by X-ray diffraction and by an independent synthesis from furan 5.

Language: English

DOI: 10.1070/MC1997v007n02ABEH000708

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