R. Becerra, S. E. Boganov, M. P. Egorov, O. M. Nefedov, R. Walsh, “Direct time-resolved study of the kinetics of the gas-phase reaction of germylene with triethylgermane: a negative activation energy for the Ge–H insertion process”, Mendeleev Commun., 1997, Volume 7, Issue 3,Pages <nobr>87

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Direct time-resolved study of the kinetics of the gas-phase reaction of germylene with triethylgermane: a negative activation energy for the Ge–H insertion process

R. Becerra^a, S. E. Boganov^b, M. P. Egorov^b, O. M. Nefedov^b, R. Walsh^c

^a Instituto Quimica Fisica 'Rocasolano',Madrid, Spain
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c Department of Chemistry, University of Reading, UK

Abstract: Gas-phase rate constants, obtained from 292–557 K, yield an activation energy of –10.6±1.1 kJ mol^–1 for the insertion reaction of GeH₂ into a Ge–H bond (of triethylgermane); these results indicate the likely involvement of an intermediate complex.

Language: English

DOI: 10.1070/MC1997v007n03ABEH000787