S. I. Gorbin, A. A. Bakibaev, D. A. Kurgachev, V. S. Malkov, K. Yu. Novolokov, G. O. Sysoev, “Synthesis of 1-[1-(diphenoxyphosphoryl)alkyl]-3,4,6-trimethylglycolurils”, Mendeleev Commun., 2023, Volume 33, Issue 5,Pages <nobr>638

This article is cited in 3 papers

Communications

Synthesis of 1-[1-(diphenoxyphosphoryl)alkyl]-3,4,6-trimethylglycolurils

S. I. Gorbin, A. A. Bakibaev, D. A. Kurgachev, V. S. Malkov, K. Yu. Novolokov, G. O. Sysoev

Department of Chemistry, National Research Tomsk State University, Tomsk, Russian Federation

Abstract: The reaction of 1,3,4-trimethylglycoluril, aliphatic aldehydes and triphenyl phosphite in the presence of methanesulfonic acid affords new phosphorus-containing derivatives of glycoluril. The thus formed diastereomers of 1-[1-(diphenoxy-phosphoryl)alkyl]-3,4,6-trimethylglycolurils were separated by reverse-phase HPLC

Keywords: 1,3,4-trimethylglycolurils, phosphonates, diastereomers, Birum-Oleksyszyn reaction, triphenyl phosphite, one-pot synthesis.

Language: English

DOI: 10.1016/j.mencom.2023.09.015

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