V. D. Kolesnik, M. M. Shakirov, A. V. Tkachev, “Synthesis of diethyl oxo phosphonates from monoterpene ketones – carvone, pinocarvone and 2-caren-4-one”, Mendeleev Commun., 1997, Volume 7, Issue 4,Pages <nobr>141

This article is cited in 7 papers

Synthesis of diethyl oxo phosphonates from monoterpene ketones – carvone, pinocarvone and 2-caren-4-one

V. D. Kolesnik^a, M. M. Shakirov^b, A. V. Tkachev^b

^a Department of Natural Sciences, Novosibirsk State University, Novosibirsk, Russian Federation
^b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: Reaction of α,β-unsaturated monoterpenic ketones – carvone, pinocarvone and 2-caren-4-one – with the sodium salt of diethylphosphite in diethylphosphite media results in regioselective addition to the conjugated carbon–carbon double bond and formation of the corresponding oxophosphonates.

Language: English

DOI: 10.1070/MC1997v007n04ABEH000764