G. M. Khrapkovskii, A. G. Shamov, G. A. Shamov, V. A. Shlyapochnikov, “A theoretical study of the formation and destruction of the aci-forms of nitromethane and dinitromethane”, Mendeleev Commun., 1997, Volume 7, Issue 5,Pages <nobr>169

This article is cited in 12 papers

A theoretical study of the formation and destruction of the aci-forms of nitromethane and dinitromethane

G. M. Khrapkovskii^a, A. G. Shamov^a, G. A. Shamov^a, V. A. Shlyapochnikov^b

^a Kazan National Research Technological University, Kazan, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A quantum-chemical study of the dehydration mechanism of CH₃NO₂ and CH₂(NO₂)₂ molecules has shown that a water molecule eliminates from the respective aci-forms, formation of the latter being the limiting step of the whole process.

Language: English

DOI: 10.1070/MC1997v007n05ABEH000825