P. A. Stuzhin, M. Hamdush, H. Homborg, “Formation of heterobinuclear μ-nitrido complexes with a Mn–N–Fe moiety by reaction of nitrido(octaphenyltetraazaporphyrinato)manganese(V) with iron(III) porphyrins”, Mendeleev Commun., 1997, Volume 7, Issue 5,Pages <nobr>196

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Formation of heterobinuclear μ-nitrido complexes with a Mn–N–Fe moiety by reaction of nitrido(octaphenyltetraazaporphyrinato)manganese(V) with iron(III) porphyrins

P. A. Stuzhin^a, M. Hamdush^b, H. Homborg^c

^a Department of Organic Chemistry, Ivanovo State University of Chemical Technology, Ivanovo, Russian Federation
^b Department of Organic Chemistry, State Academy of Chemistry and Technology, Ivanovo, Russian Federation
^c Institut fuer Anorganische Chemie, Christian-Albrechts-Universitaet zu Kiel, Kiel, Germany

Abstract: Nitrido(octaphenyltetraazaporphyrinato)manganese(V) (N≡MnOPTAP) obtained by treatment of chlorine on acido(octaphenyltetraazaporphyrinato) manganese(III) [(X)MnOPTAP; X = Cl, AcO, HSO₄] in chloroform solution saturated with ammonia, reacts with acido(octaphenyltetraazaporphyrinato)iron(III) [(X)FeOPTAP; X = Cl, Br, AcO] forming the heterometallic μ-nitrido complex μ-(MnNFe)(OPTAP)₂; μ-nitrido complexes with a dissimilar porphyrin ligand on each metal have also been prepared.

Language: English

DOI: 10.1070/MC1997v007n05ABEH000819