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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 1996 Volume 6, Issue 2, Pages 57–59 (Mi mendc4913)

This article is cited in 2 papers

Interaction of an NO + O2 gas mixture with Cu/ZSM-5 catalyst, studied by EPR and TPD

A. N. Il'ichev, A. A. Ukharsky, V. A. Matyshak

N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: At 293 K the NO2 molecules formed in an NO + O2 gas mixture are found to oxidize the copper ions in Cu/ZSM-5 from Cu+ to Cuisol2+ and to become stabilized on isolated Cuisol2+ions at temperatures < 620 K, changing the coordination of the latter to a square planar configuration in which one of the ligands is the NO2 molecule.

Language: English

DOI: 10.1070/MC1996v006n02ABEH000579



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