R. G. Kostyanovsky, V. A. Korneev, I. I. Chervin, V. N. Voznesensky, Yu. V. Puzanov, P. Rademacher, “1,2-Di-<i>tert</i>-butyldiaziridine”, Mendeleev Commun., 1996, Volume 6, Issue 3,Pages <nobr>106

This article is cited in 13 papers

1,2-Di-tert-butyldiaziridine

R. G. Kostyanovsky^a, V. A. Korneev^a, I. I. Chervin^a, V. N. Voznesensky^a, Yu. V. Puzanov^a, P. Rademacher^b

^a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^b Institute of Organic Chemistry, University of Essen, Germany

Abstract: 1,2-Di-tert-butyldiaziridine 1 has been synthesized for the first time and its ¹H and ¹³C NMR spectra studied in comparison with model diaziridines 8–10. Its photoelectron and mass spectra have been measured and its structure optimized by semiempirical and ab initio calculations; considerable steric deformation of the CH₂ ring fragment and mutual approach of tert-butyl groups is shown.

Language: English

DOI: 10.1070/MC1996v006n03ABEH000601