A. L. Chistyakov, I. V. Stankevich, I. S. Akhrem, N. P. Gambaryan, M. E. Vol'pin, “Superelectrophiles generated in mBr2 nAlBr3 systems”, Mendeleev Commun., 1996, Volume 6, Issue 5,Pages 175

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Superelectrophiles generated in mBr₂ nAlBr₃ systems

A. L. Chistyakov, I. V. Stankevich, I. S. Akhrem, N. P. Gambaryan, M. E. Vol'pin

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: MNDO/PM3 calculations have proved the possibility of the existence in mBr₂ nAlBr₃ systems of highly electrophilic complexes with bidentate coordination of AlBr4-anions with a positively charged (up to + 1.45 a.u.) Br atom.

Language: English

DOI: 10.1070/MC1996v006n05ABEH000632