V. M. Mamaev, I. P. Gloriozov, A. V. Prisyajnuk, Yu. A. Ustynyuk, “Influence of tunnelling on the ratio of the activation rate constants of C–C and C–H bonds in ethane by a bare palladium atom”, Mendeleev Commun., 1996, Volume 6, Issue 5,Pages <nobr>203

This article is cited in 5 papers

Influence of tunnelling on the ratio of the activation rate constants of C–C and C–H bonds in ethane by a bare palladium atom

V. M. Mamaev^a, I. P. Gloriozov^a, A. V. Prisyajnuk^b, Yu. A. Ustynyuk^a

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Far Eastern Federal University, Vladivostok, Russian Federation

Abstract: Dynamic modeling of ethane oxidative insertion to a bare palladium atom at both C–C and C–H bonds has demonstrated the influence of quantum effects in the more growth of the rate constant of C–H bond activation compared to C–C activation.

Language: English

DOI: 10.1070/MC1996v006n05ABEH000647