E. I. Troyanskii, R. F. Ismagilov, E. N. Korneeva, M. S. Pogosyan, G. I. Nikishin, “An Approach to 8-, 16- and 24-Membered Sulfur-containing Heterocycles <i>via</i> Homolytic Cycloaddition of Alkynes with Butane-1,4-dithiol”, Mendeleev Commun., 1995, Volume 5, Issue 1,Pages <nobr>18–20</nobr>

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Mendeleev Commun., 1995 Volume 5, Issue 1, Pages 18–20 (Mi mendc5015)

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An Approach to 8-, 16- and 24-Membered Sulfur-containing Heterocycles via Homolytic Cycloaddition of Alkynes with Butane-1,4-dithiol

E. I. Troyanskii^a, R. F. Ismagilov^b, E. N. Korneeva^b, M. S. Pogosyan^a, G. I. Nikishin^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Abstract: Homolytic cycloaddition of butane-1,4-dithiol with alkynes offers a facile one-pot route to 8-membered 1,4-dithiocanes and 16-and 24-membered crown thioethers, 1,4,9,12-tetrathiacyclohexadecanes and 1,4,9,12,17,20-hexathiacyclotetracosanes.

Language: English

DOI: 10.1070/MC1995v005n01ABEH000441

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