N. N. Makhova, A. N. Blinnikov, L. I. Khmel'nitskii, “The Schmidt Rearrangement of Methyl Furoxanyl Ketones and Furoxancarboxylic Acids: a New Synthetic Route to Aminofuroxans”, Mendeleev Commun., 1995, Volume 5, Issue 2,Pages <nobr>56

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The Schmidt Rearrangement of Methyl Furoxanyl Ketones and Furoxancarboxylic Acids: a New Synthetic Route to Aminofuroxans

N. N. Makhova, A. N. Blinnikov, L. I. Khmel'nitskii

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The Schmidt rearrangement of methyl furoxanyl ketones and furoxancarboxylic acids has been carried out for the first time, exemplified by 3,4-diacetylfuroxan and 4-carboxy-3-(ethoxycarbonyl)furoxan, and this reaction has been shown to be a convenient method for the preparation of aminofuroxans.

Language: English

DOI: 10.1070/MC1995v005n02ABEH000455